Functional groups are atoms or small groups of atoms (two to four) that exhibit a characteristic reactivity when treated with certain reagents. A particular functional group will almost always display its characteristic chemical behavior when it is present in a compound. Because of their importance in understanding organic chemistry, functional groups have characteristic names that often carry over in the naming of individual compounds incorporating specific groups. In the following table the atoms of each functional group are colored red and the characteristic IUPAC nomenclature suffix that denotes some (but not all) functional groups is also colored.
Group Formula |
Class Name | Specific Example | IUPAC Name | Common Name |
---|---|---|---|---|
Alkene | H2C=CH2 | Ethene | Ethylene | |
Alkyne | HC≡CH | Ethyne | Acetylene | |
Arene | C6H6 | Benzene | Benzene |
Group Formula |
Class Name |
Specific Example |
IUPAC Name |
Common Name |
---|---|---|---|---|
Halide | H3C-I | Iodomethane | Methyl iodide | |
Alcohol | CH3CH2OH | Ethanol | Ethyl alcohol | |
Ether | CH3CH2OCH2CH3 | Diethyl ether | Ether | |
Amine | H3C-NH2 | Aminomethane | Methylamine | |
Nitro Compound | H3C-NO2 | Nitromethane | ||
Thiol | H3C-SH | Methanethiol | Methyl mercaptan | |
Sulfide | H3C-S-CH3 | Dimethyl sulfide |
Group Formula |
Class Name |
Specific Example |
IUPAC Name |
Common Name |
---|---|---|---|---|
Nitrile | H3C-CN | Ethanenitrile | Acetonitrile | |
Aldehyde | H3CCHO | Ethanal | Acetaldehyde | |
Ketone | H3CCOCH3 | Propanone | Acetone | |
Carboxylic Acid | H3CCO2H | Ethanoic Acid | Acetic acid | |
Ester | H3CCO2CH2CH3 | Ethyl ethanoate | Ethyl acetate | |
Acid Halide | H3CCOCl | Ethanoyl chloride | Acetyl chloride | |
Amide | H3CCON(CH3)2 | N,N-Dimethylethanamide | N,N-Dimethylacetamide | |
Acid Anhydride | (H3CCO)2O | Ethanoic anhydride | Acetic anhydride |